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25. M Müller-Lorenz; A. Schneider: ISIJ Int. 41 (2001) Supplement S1– S8. 26. ; J. Zhang and G. Inden: Corrosion Sci. 44 (2002) 2353, 45 (2003) 281. 27. Forseth, S. J. Grabke: unpublished. 28. D. A. Ramanarayanan: J. Electrochem. Soc. 147 (2000) 3680–3686. 29. M. J. Grabke: Mat. Corr. 50 (1999) 614–621. 30. ; R. J. Grabke: Mat. Corr. 50 (1999) 622–627. 31. : CRC Crit. Rev. Solid State Mater. Sci. (1978) 333–355. 32. ; R. M. Müller-Lorenz: Werkst. und Korr. 44 (1993) 89– 97. 33. M. Müller-Lorenz; B.

Pippel et al. [11] and Chun et al. [12–15] have significantly extended the understanding of the micro-mechanistic aspects of metal dusting of pure metals by transmission electron microscopy (TEM). The Hochman proposal for the metal dusting corrosion of iron, which has been further refined by Grabke and coworkers, involves the initial formation of a metastable Fe3C carbide layer on the iron surface in the carbonsupersaturated environment. The carbide subsequently dissociates into carbon and metal particles when it is destabilized by carbon deposition, leading to the formation of ‘dust’.

16. R. J. Grabke: Archiv Eisenhüttenwes. 49 (1978) 129–133. 24 Corrosion by carbon and nitrogen 17. Meschter, P. J. Grabke: Metallurg. Trans. 10B (1979) 323–329. 18. Münster, P. J. Grabke: Berichte Bunsenges. Phys. Chem. 84 (1980) 1068– 1071. 19. Münster, P. J. Grabke: Archiv Eisenhüttenwes. 51 (1980) 319–324. 20. D. A. Ramanarayanan: Mat. Corr. 50 (1999) 634– 639. 21. L. Fearing; J. A. Ruth and G. Simkovich: Solid State Ionics 12 (1984) 145–151. 22. ; G. J. Grabke; Q. Wei; E. Pippel and J. Woltersdorf: Steel Research 71 (2000) No.

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